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Research Area

Novel Photonic Materials Based on Charge . Ordered Manganese Oxides

Advisor: Dr. Vera Smolyaninova

Current demands in the areas of computing and communication require increasing speed of computation and information transfer. One solution is to replace "slow" electronic devices with "fast" photonic ones. This requires the development of optical analogues of electronic integrated circuits capable of routing, controlling and processing optical signals. One of the promising approaches is based on photonic band-gap materials, which allow control of dispersion and propagation of light. A photonic band-gap may appear in a three-dimensional photonic crystal (a material with periodic modulation of refractive index with a period of the order of the wavelength of light). Inside a photonic crystal transmission or rejection of light in a given wavelength range and wave guiding of light along linear and bent defects of a periodic photonic crystal structure can be achieved. The necessary condition for the photonic band gap to appear is high (more than 2 to 1) refractive index contrast within the photonic crystal. Creation of a photonic band-gap material is a very difficult technological task.

Mixed valence manganese oxides exhibit unique photosensitivity properties, such as permanent photo- induced reflectivity changes due to local photoinduced insulator to metal transition. As a result, nanostructuring of these materials may be performed using well-known optical holography techniques. Unique and novel feature of this experimental program is based on the extreme sensitivity of the manganite materials to external fields, such as magnetic field, temperature, external illumination, etc. Recently, permanent photoinduced reflectivity changes in manganites were demonstrated by Dr. Smolyaninova. This sensitivity will be used to .develop. the holograms: application of the external fields will result in substantial enhancement of the weak initial refractive index contrast of the holograms, resulting in the potential appearance of photonic band gaps. On the other hand, such photoinduced photonic crystal structures may be easily annealed using, for example, intense light, so that new structures can be written in the same region of the sample instead of the old ones. Thus, unique writable and erasable photonic crystal materials may potentially be created. Such materials would be invaluable in numerous photonic device applications.

The REU participants will be involved in every step of this research program. In order to create photonic structures, 500-1000 nm thin films of Bi1-xCaxMnO3 are needed. These thin films will be grown in the Material Research Lab at Towson University using a Pulsed Laser Deposition (PLD) system. Students will be trained to use the PLD system. For the photonic device application thin films of good quality, which posses the charge ordering, are needed. These thin films have to be characterized in order to find appropriate growth conditions for desirable properties. Since these materials have a sharp upturn in the temperature dependence of the resistivity, transport measurements will be a key measurement in the sample characterization. Thin films will be characterized over a wide temperature range using a closed cycle cryostat. Participants will be trained in transport measurement techniques in the temperature range from room to liquid helium temperatures.

As a first step toward development of photonic crystals, one-dimensional (1D) photonic structures, which consist of a series of illuminated channels, will be created. Optical reflectivity of these channels will be studied using a near field scanning optical microscope (NSOM), which is being developed at Towson University by Dr. Smolyaninova. Students will be trained to use this unique scanning technique. Temperature and magnetic field dependence of electrical conductivity of illuminated channels will be studied, since local photoinduced insulator to metal transition is expected. A study of temperature and magnetic field dependence of the conductivity of such channels will be useful for controlling the optical contrast, since metallic regions are supposed to have higher optical reflectivity. Since magnetism and conductivity are closely connected in manganites, local changes in magnetic structure are expected. Local magnetic structure will be studies with commercial magnetic force microscope (MFM) in the Nanotechnology Laboratory at Towson University.

After successful development of 1D photonic structures, this work can be extended to 2D photonic structures using NSOM. The reflectivity, local magnetic structure and conductivity of these structures will be tested using various scanning techniques (NSOM, MFM, and STM). In addition, prototype switchable photonic crystal devices will be created and tested.

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+ Metal Oxide Thin Films
+ Photonic Materials
+ Nanotechnology
+ Biomaterials
+ Raman Spectroscopy
+ Electrochemistry
+ EPR Studies

Dr. David M. Schaefer (PI)
Dr. David Larkin (COPI)
Dr. Steven Lev (COPI)
Dr. Boon Loo (COPI)
Dr. Raj.  Moolathody (COPI)
Dr. Lev Ryzhkov (COPI)
Dr. Vera Smolyaninova (COPI)


Dr. David Schaefer
Tel:    410-704-3007
Fax:   410-704-3511
Email